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Download PDF by W. Suski, T. Palewski (auth.), H.P.J. Wijn (eds.): Binary Lanthanide Oxides

By W. Suski, T. Palewski (auth.), H.P.J. Wijn (eds.)

ISBN-10: 3540471871

ISBN-13: 9783540471875

ISBN-10: 3540529608

ISBN-13: 9783540529606

In subvolume 27C1 magnetic and comparable houses of binary lanthanide oxides were compiled. This subvolume covers information acquired considering the fact that 1980 and will consequently be considered as complement to quantity III/12c. whereas within the earlier quantity nearly all of magnetic facts was once bought both from magnetometric measurements or from neutron diffraction, for the current info the most emphasis is dedicated to "related" houses with out which, notwithstanding, the knowledge of classical magnetic homes is very unlikely. A moment half 27C2 will take care of binary oxides of the actinide elements.

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C. The reflectivity spectra in the photon energy region from 100 to 115 eV at RT [87MFKS]. It is the enlarged view of the multiplet component at the prethreshold region (see Fig. 34). The broken line corresponds to the results of the sample partially deoxidized in the atmosphere at 900 °C. This line clearly indicates the mixture of intrinsic CeO2 and Ce2O3. Fig. 36. c. Dielectric functions (ε = ε1 − iε2) obtained from reflectivity spectrum (see Fig. 33) for a stoichiometric single crystal in the low-energy photon range at 300 K [87MW].

The overall profile of the feature b for the resonance at the giant-absorption band resembles that of the satellite a, which is ascribed to the 4f state of the trivalent Ce ion. The feature c shows a shoulder at 128 eV as well as a small enhancement at 124 eV . This suggests that the feature c includes other components than the 4f state and may show the enhancement due to the 5d component in the valence band. Judging from the profiles of the spectrum of the feature b and the off-resonance EDC, the Ce 5d component might contribute to the enhancement of the feature by at most 30 % of the total enhancement at the 124 eV photoexcitation.

7 eV. Agreement between PSD and PEY show similar oxidation states in the surface and in the bulk for samarium and praseodymium oxides. 4 Figures and tables [Ref. p. 121 Fig. 50. Pr6O11. Background corrected inelastic neutron scattering spectra for T = 5, 80 and 170 K [92Ho]. Except for the hatched areas which correspond to the nuclear incoherent elastic scattering, the scattering is of magnetic origin. Obviously, there exist two different types of magnetic responses. One is rather broad, as indicated by the dashed line and the other consists of a few very sharp inelastic excitations.

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Binary Lanthanide Oxides by W. Suski, T. Palewski (auth.), H.P.J. Wijn (eds.)

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